by Staff Writers
Oak Ridge TN (SPX) Nov 11, 2014
Scientists at the Department of Energy's Oak Ridge National Laboratory have made the first direct observations of a one-dimensional boundary separating two different, atom-thin materials, enabling studies of long-theorized phenomena at these interfaces.
Theorists have predicted the existence of intriguing properties at one-dimensional (1-D) boundaries between two crystalline components, but experimental verification has eluded researchers because atomically precise 1-D interfaces are difficult to construct.
"While many theoretical studies of such 1-D interfaces predict striking behaviors, in our work we have provided the first experimental validation of those interface properties," said ORNL's An-Ping Li.
The new Nature Communications study builds on work by ORNL and University of Tennessee scientists published in Science earlier this year that introduced a method to grow different two-dimensional materials - graphene and boron nitride - into a single layer only one atom thick.
The team's materials growth technique unlocked the ability to study the 1-D boundary and its electronic properties in atomic resolution. Using scanning tunneling microscopy, spectroscopy and density-functional calculations, the researchers first obtained a comprehensive picture of spatial and energetic distributions of the 1-D interface states.
"In three-dimensional (3-D) systems, the interface is embedded so you cannot get a real-space view of the complete interface - you can only look at a projection of that plane," said Jewook Park, ORNL postdoctoral researcher and the lead author of the work. "In our case, the 1-D interface is completely accessible to real-space study,"
"The combination of scanning tunneling microscopy and the first principles theory calculations allows us to distinguish the chemical nature of the boundary and evaluate the effects of orbital hybridization at the junction," said ORNL's Mina Yoon, a theorist on the team.
The researchers' observations revealed a highly confined electric field at the interface and provided an opportunity to investigate an intriguing phenomenon known as a "polar catastrophe," which occurs in 3-D oxide interfaces. This effect can cause atomic and electron reorganization at the interface to compensate for the electrostatic field resulting from materials' different polarities.
"This is the first time we have been able to study the polar discontinuity effect in a 1-D boundary," Li said.
Although the researchers focused on gaining a fundamental understanding of the system, they note their study could culminate in applications that take advantage of the 1-D interface.
"For instance, the 1-D chain of electrons could be exploited to pass a current along the boundary," Li said. "It could be useful for electronics, especially for ultra-thin or flexible devices."
The team plans to continue examining different aspects of the boundary including its magnetic properties and the effect of its supporting substrate.
Oak Ridge National Laboratory
Space Technology News - Applications and Research
|The content herein, unless otherwise known to be public domain, are Copyright 1995-2014 - Space Media Network. All websites are published in Australia and are solely subject to Australian law and governed by Fair Use principals for news reporting and research purposes. AFP, UPI and IANS news wire stories are copyright Agence France-Presse, United Press International and Indo-Asia News Service. ESA news reports are copyright European Space Agency. All NASA sourced material is public domain. Additional copyrights may apply in whole or part to other bona fide parties. Advertising does not imply endorsement, agreement or approval of any opinions, statements or information provided by Space Media Network on any Web page published or hosted by Space Media Network. Privacy Statement All images and articles appearing on Space Media Network have been edited or digitally altered in some way. Any requests to remove copyright material will be acted upon in a timely and appropriate manner. Any attempt to extort money from Space Media Network will be ignored and reported to Australian Law Enforcement Agencies as a potential case of financial fraud involving the use of a telephonic carriage device or postal service.|